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Quick Answer — Sodium Metabisulphite (SMBS / Sodium Pyrosulfite) 97–98% Technical & Food Grade

Sodium Metabisulphite (Na2S2O5 98%) is an inorganic chemical reducing agent used as an antichlor in reverse osmosis water treatment, a cyanide destruction agent in gold mining leaching, and a preservative (E223) in food processing. Kiki's supplies 25kg bags and bulk quantities across Kenya.

Sodium Metabisulphite is a white crystalline inorganic salt consisting of sodium disulfite ions, valued for its rapid oxygen-scavenging, chlorine-neutralizing, and microbial preservation properties.

Key Facts

  • Chemical Formula: Na2S2O5 (CAS 7681-57-4)
  • Minimum Assay: 97.0% – 98.0% active Na2S2O5
  • Available SO2 Content: 65.0% min by weight
  • Solubility: 650 g/L in water at 20°C
  • Primary Industrial Uses: Gold mining cyanide detox, RO dechlorination, food preservation (E223), leather tanning

Primary Use Cases

Reverse Osmosis water feed dechlorinationGold CIL/CIP tailings cyanide neutralizationFood & beverage preservation & antioxidantTextile antichlor & bleaching agentLeather tanning chrome reduction
Sodium Metabisulphite (SMBS / Sodium Pyrosulfite) 97–98% Technical & Food Grade
Mining Chemicals & Flotation

Sodium Metabisulphite (SMBS / Sodium Pyrosulfite) 97–98% Technical & Food Grade

Product Code: KIC-MIN-202

Also known as: Sodium Metabisulphite, Sodium Pyrosulfite, Sodium Disulfite, SMBS, E223

Synonyms: Disodium Disulfite, Pyrosulfurous Acid Sodium Salt, Sodium Metabisulfite (Na2S2O5)

High-purity Sodium Metabisulphite (Na2S2O5 98%) used as a powerful reducing agent, antichlor, oxygen scavenger in water treatment, wine/food preservative (E223), and cyanide destruction agent in gold mining leaching.

CAS Number
7681-57-4
Formula
Na2S2O5
IUPAC Name
disodium oxido-oxosulfanyloxysulfane
Molecular Weight
190.10 g/mol
EC Number
231-673-0
UN Number
UN 2693
Chemical Family
Inorganic Sulfite / Reducing Agent
Grade
Industrial Grade
Purity
97.0%–98.0% min
Physical Form
Powder

Available Packaging

25 / 1200kg bags

Product Overview

Sodium Metabisulphite (Na2S2O5, CAS 7681-57-4), also known as sodium pyrosulfite or SMBS, is a white crystalline powder with a faint sulfur dioxide odour. It is an essential inorganic reducing agent widely utilized across East Africa in mining (cyanide neutralization), water treatment (dechlorination and RO membrane protection), food & beverage processing (E223 preservative and antioxidant), textile processing, and leather tanning.

Technical Description

In aqueous solution, Sodium Metabisulphite reacts with water to release bisulfite ions (HSO3-) and sulfur dioxide (SO2). This rapid reduction mechanism makes it ideal for neutralizing residual chlorine and chloramines in industrial water treatment prior to reverse osmosis (RO) filtration, preventing polyamide membrane oxidation. In gold leaching plants, SMBS is dissolved to supply SO2 for the INCO SO2/air cyanide destruction process, rapidly degrading free and WAD cyanides into less toxic cyanate ions.

Complete Chemical Specifications

Commercial Specification
96% min [Method: Standard COA]
Physical Form
Powder [Method: Visual]
Chemical Formula
Na2S2O5 [Method: XRD / NMR]
Molecular Weight
190.10 g/mol [Method: Calculated]

Physical & Chemical Properties

Appearance
White to light yellow crystalline powder
Odour
Pungent, sulfurous SO2 odour
pH
4.0 – 4.8 (5% aqueous solution at 20°C)
Density
1.48 g/cm³ (bulk density ~1.2–1.3 g/cm³)
Boiling Point
Decomposes above 150°C without boiling
Melting Point
Decomposes at 150°C (302°F)
Solubility
Soluble in water (650 g/L at 20°C); slightly soluble in ethanol

Commercial Availability

Stock Status
InStock
Lead Time
Same-day dispatch in Nairobi / 24-48 hrs countrywide Kenya
MOQ
25 kg bag
Delivery Regions
Nairobi, Mombasa, Kisumu, Eldoret, Nakuru, East Africa (Uganda, Tanzania, Rwanda)

Contact Kiki's sales engineering team for COA batch verification, bulk volume pricing, or technical dosing guidance.

Suitable Applications

Target Industries

Use Cases

  • RO membrane dechlorination antichlor in water treatment plants
  • Cyanide destruction in gold mining CIL/CIP tailings effluent
  • Food & beverage antioxidant and preservative (E223)
  • Reducing agent in textile dyeing and bleaching processes
  • Chrome reduction and bleaching in leather tanning operations
  • Oxygen scavenger in oilfield water injection systems

Storage Guidelines

Store in a cool, dry, well-ventilated warehouse away from direct sunlight, moisture, strong acids, and oxidizing agents. Keep containers tightly sealed in moisture-proof polyethylene-lined bags. Avoid temperatures above 50°C to prevent thermal decomposition and toxic sulfur dioxide gas evolution.

Handling Advisory

Wear full personal protective equipment including chemical splash goggles, half-mask respirator with sulfur dioxide/dust cartridges, nitrile gloves, and protective coveralls. Avoid dust generation and inhalation. In case of spills, sweep dry material into clean, labelled containers without creating airborne dust; neutralize residue with dilute sodium carbonate solution.

Safety & Chemical Handling Advisory

Safety Advisory

Eye contact: Immediately flush with running water for 15+ minutes holding eyelids open; seek urgent medical aid. Skin contact: Wash thoroughly with soap and water; remove contaminated clothes. Inhalation: Move victim to fresh air; administer oxygen if breathing is difficult. Ingestion: Rinse mouth with water; do NOT induce vomiting; seek immediate medical advice.

GHS:Acute Tox. 4 (Oral), Eye Dam. 1, Aquatic Acute 3
Signal Word:DANGER
Transport:UN 2693, Class 8 (Corrosive Solids, Acidic, Inorganic, N.O.S.) / Non-restricted in dry packaged quantities under 500kg per local ADR guidelines
Packing Group:PG III

Hazard Statements

  • H302: Harmful if swallowed
  • H318: Causes serious eye damage
  • EUH031: Contact with acids liberates toxic gas (sulfur dioxide)

Precautionary Statements

  • P280: Wear protective gloves/protective clothing/eye protection/face protection
  • P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell
  • P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing

PPE Requirements

Chemical safety goggles & face shieldHalf-face respirator with SO2/P3 dust filtersHeavy-duty nitrile or neoprene glovesProtective apron or chemical suitSafety boots

COMMERCIAL & TECHNICAL GUIDANCE

Frequently Asked Questions — Sodium Metabisulphite (SMBS / Sodium Pyrosulfite) 97–98% Technical & Food Grade

Technical, regulatory, and supply guidance for Sodium Metabisulphite (SMBS / Sodium Pyrosulfite) 97–98% Technical & Food Grade.

Sodium Metabisulphite (SMBS) is used as a primary source of sulfur dioxide (SO2) in the INCO SO2/air cyanide destruction process. It oxidizes toxic free and WAD cyanides in gold leach tailings into environmentally safe cyanate ions prior to discharge into tailings storage facilities.

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